Trimethylsilyl trifluoromethanesulphonate, also knows as Trimethylsilyl triflate or {[(Trifluoromethyl)sulphonyl]oxy}trimethylsilane, is an organosilicon.
In trifluoroacetic, it has been found to cleave, in the presence of thioanisole, a number of protecting groups currently employed in pep... Read More
Trimethylsilyl trifluoromethanesulphonate, also knows as Trimethylsilyl triflate or {[(Trifluoromethyl)sulphonyl]oxy}trimethylsilane, is an organosilicon.
In trifluoroacetic, it has been found to cleave, in the presence of thioanisole, a number of protecting groups currently employed in peptide synthesis, without significant side reactions and with a much faster rate of reaction than trifluoromethanesulphonic acid in trifluoroacetic acid. This new deprotecting reagent has been used in solution and solid phase peptide syntheses of nueromedin U-25 (a 25-residue peptide) and a rabit stomach peptide (an 8-residue peptide), respectively.
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