Bis[tris(tert-butyl)phosphine]palladium, 19.6% Pd

CAS: 53199-31-8 | OR17884 | Bis[tris(tert-butyl)phosphine]palladium, 19.6% Pd

Catalogue Number OR17884

Synonym(s):

Bis[tris(tert-butyl)phosphine]palladium (Cas Number 53199-31-8) is a Palladium catalyst widely utlised for Coupling reactions and greener Heck reactions in TPGS-750-M. It acts as a palladium catalyst for reductive carbonylation.

Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst... Read More

CAS Number

53199-31-8

Commodity Code

2843909000

MDL Number

MFCD03094580

Formula Weight
511.05 g/mol
Melting Point
258-272 °C
MSDS
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Typical Batch COA
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250mg
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Out of Stock
£16.00
1g
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Out of Stock
£42.00
5g
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Out of Stock
£175.00
Size 250mg
Price £16.00
UK Stock In Stock
US Stock Out of Stock
Size 1g
Price £42.00
UK Stock In Stock
US Stock Out of Stock
Size 5g
Price £175.00
UK Stock 2 Packs in stock.
US Stock Out of Stock

Product Description

Bis[tris(tert-butyl)phosphine]palladium (Cas Number 53199-31-8) is a Palladium catalyst widely utlised for Coupling reactions and greener Heck reactions in TPGS-750-M. It acts as a palladium catalyst for reductive carbonylation.

Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides, it is also used for:

  • Cross-coupling of aryl and vinyl chlorides.
  • Amination of aryl chlorides and bromides using aqueous hydroxide bases.
  • Cross-coupling of heteroaromatic carboxylic acids.
  • Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
  • Cross-coupling of silanolates and halides.
  • Elimination/isomerization of enol triflates derived from β-ketoesters.

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